(N,N-diethyl-O-ethylammonium)ferrocenyldithiophosphonate | 786695-22-5

• 英文名称: (N,N-diethyl-O-ethylammonium)ferrocenyldithiophosphonate
• 英文别名: Et2[(O-ethylammonium)ferrocenyldithiophosphonate]
• CAS: 786695-22-5
• 化学式: C₁₆H₂₄FeNOPS₂
• 分子量: 397.325
• InChiKey: BSSOHULUVPENNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,4-diferrocenyl-1,3-dithiadiphosphetane-2,4-disulfide 、 二乙氨基乙醇 以 甲苯 为溶剂， 以68%的产率得到(N,N-diethyl-O-ethylammonium)ferrocenyldithiophosphonate
  参考文献：
  名称：

  Zwitterionic ferrocenyldithiophosphonates: the molecular structure of [FcP(S)S(OCH2CH2NH2Me)] [Fc=Fe(η5-C5H4)(η5-C5H5)]

  摘要：

  Ferrocenyldithiodiphosphetane [FcPS(mu-S)](2) [Fc = Fe(eta(5)-C5H4)(eta(5)-C5H5)] reacts with the aminoethanol derivatives HOCH2CH2NHMe and HOCH2CH2NEt2 to give the first structurally characterised examples of zwitterionic (O-ethylammonium)ferrocenyldithiophosphonates, [FcP(S)S((OCH2CH2NHRR2)-R-1)] (R-1 = H, R-2 = Me (1); R-1 = R-2 = Et (2)). 1 and 2 were characterised by elemental analyses, IR, NMR spectroscopy (H-1, C-13 (for 2) and P-31) and mass spectrometry. A crystal structure determination was carried out on 1. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.07.003