1'-(3-methyl-5-oxocyclohex-3-enyl)ferrocenecarboxylic acid | 1615713-73-9

• 英文名称: 1'-(3-methyl-5-oxocyclohex-3-enyl)ferrocenecarboxylic acid
• CAS: 1615713-73-9
• 化学式: C₁₈H₁₈FeO₃
• 分子量: 338.186
• InChiKey: XVZVZKYHFUTGGM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1'-[(E)-3-oxo-but-1-enyl]ferrocenecarboxylic acid 、 丙二酸二乙酯 在 sodium 作用下， 以 乙醇 为溶剂， 以35%的产率得到1'-(3-methyl-5-oxocyclohex-3-enyl)ferrocenecarboxylic acid
  参考文献：
  名称：

  A simple method for desymmetrizing 1,1′-ferrocenedicarboxaldehyde

  摘要：

  A simple chromatography-free method for desymmetrizing ferrocene is described starting from the readily available dialdehyde. Oxidation of 1,1'-ferrocenedicarboxaldehyde in a water/acetonitrile mixture with KMnO4 produced 1'-formyl-ferrocenecarboxylic acid. The same reaction carried out in a water/acetone mixture produced 1'-[(E)-3-oxo-but-1-enyl]-ferrocenecarboxylic acid. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.05.040