(乙酰丙酮)2SnCl(叠氮化物) | 1078725-12-8

• 中文名称: (乙酰丙酮)2SnCl(叠氮化物)
• 英文名称: (acetylacetonate)2SnCl(azide)
• 英文别名: (Acac)2SnCl(N3)
• CAS: 1078725-12-8
• 化学式: C₁₀H₁₄ClN₃O₄Sn
• 分子量: 394.402
• InChiKey: OKVBNVWOWAUVIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (乙酰丙酮)2SnCl(叠氮化物) 以 neat (no solvent) 为溶剂， 生成 tin 、 tin(ll) chloride
  参考文献：
  名称：

  Thermolysis specifics of Tin(IV) and Tin(II) complex derivatives: Thermolysis of (Acac)2SnX2 (X = Cl, N3), (CO)5MSnCl2(thf) (M = Cr, Mo, W), (CO)5MSn(Acac)2, (CO)5MSn(SCN)2, (CH3)4N(CO)5MoSnCl3 (M = Cr, W), and (CO)2MnCpSnCl2(thf)

  摘要：

  Differential scanning calorimetry and thermogravimetry are used to study the thermolysis of following complexes: (Acac)(2)Sn(N-3)Cl (1); (Acac)(2)SnCl2 (2); (CO)(5)MSn(Acac)(2) with M = Cr (3) or W ((4)), (CO)(5)MSnCl2(thf) with M = Cr (5), Mo (6), or W (7)), (CH3)(4)N(CO)(5)MSnCl3 with M = Mo (8) or W ((9)), (CO)(2)MnCpSnCl2(thf) (10)); and (CO)(5)MSn(SCN)(2) with M = Cr (11) or W (12). The phase composition of the solid thermolysis products of compounds 1-5 and 7-12 is determined by X-ray powder diffraction. Thermolysis schemes are suggested.

  DOI：

  10.1134/s0036023607070200
• 作为产物：
  描述：

  乙酰丙酮氯化锡(IV) 、 sodium azide 以 四氢呋喃 为溶剂， 生成 (乙酰丙酮)2SnCl(叠氮化物)
  参考文献：
  名称：

  Thermolysis specifics of Tin(IV) and Tin(II) complex derivatives: Thermolysis of (Acac)2SnX2 (X = Cl, N3), (CO)5MSnCl2(thf) (M = Cr, Mo, W), (CO)5MSn(Acac)2, (CO)5MSn(SCN)2, (CH3)4N(CO)5MoSnCl3 (M = Cr, W), and (CO)2MnCpSnCl2(thf)

  摘要：

  Differential scanning calorimetry and thermogravimetry are used to study the thermolysis of following complexes: (Acac)(2)Sn(N-3)Cl (1); (Acac)(2)SnCl2 (2); (CO)(5)MSn(Acac)(2) with M = Cr (3) or W ((4)), (CO)(5)MSnCl2(thf) with M = Cr (5), Mo (6), or W (7)), (CH3)(4)N(CO)(5)MSnCl3 with M = Mo (8) or W ((9)), (CO)(2)MnCpSnCl2(thf) (10)); and (CO)(5)MSn(SCN)(2) with M = Cr (11) or W (12). The phase composition of the solid thermolysis products of compounds 1-5 and 7-12 is determined by X-ray powder diffraction. Thermolysis schemes are suggested.

  DOI：

  10.1134/s0036023607070200