| 913618-85-6

• CAS: 913618-85-6
• 化学式: C₃₆H₂₉AuFeN₃OP
• 分子量: 803.433
• InChiKey: MJPWSOQXAPITTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Au(acetylacetonato)(P(C6H5)3) 、 1-ferrocenoyl-1H-(2-aminobenzimidazole) 以 二氯甲烷 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Synthesis and ligand properties towards gold and silver of the ferrocenylamidobenzimidazole ligand

  摘要：

  The treatment of FcCOCl (Fc = (C5H5)Fe(C5H4)) With amino benzimidazole in 1: 1 or 2:1 ratio gives the ferrocenyl-amido derivatives FcCO(benzimNH(2)) or (FcCO)(2)(NHbenzim), respectively. The reactivity of FcCO(benzimNH(2)) with silver or gold complexes has been studied. The reaction with the basic gold compounds [Au(acac)(PPh3)] or [O(AuPPh3)(3)]ClO4 occurs with deprotonation of the NH2 group and coordination of one or three gold(phosphine) fragments. The treatment of this ligand with silver compounds, such as Ag(OTf) or [Ag(OTf)(PPh3)], gives the complexes of stoichiometry [Ag(OTf)L] or [Ag(OTf)(PPh3)]. The ligand FcCO(benzimNH(2)) and the complex [Ag(OTf){FcCO(benzimNH(2))}(PPh3)] have been characterized by X-ray diffraction studies. DFT calculations were performed on models of this dimeric silver complex and showed that dimerization is energetically favourable, because Ag(I) achieves a four coordination environment, despite some bonds being relatively weak. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.06.025