1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane | 102258-21-9

• 英文名称: 1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane
• 英文别名: [1,1,1-(PPh3)HCl-5,6-PPh3)2-isocloso-1-RuB9H7]
• CAS: 102258-21-9
• 化学式: C₅₄H₅₃B₉ClP₃Ru
• 分子量: 1028.76
• InChiKey: RJXXIYQCPKQJND-HYVUCUADSA-M

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 [NEt4][arachno-B9H14] 以 二氯甲烷 为溶剂， 以39%的产率得到1-chloro-1-hydrido-1,3,5-tris(triphenylphosphine)-isocloso-1-ruthenadecaborane
  参考文献：
  名称：

  Crook, Janet E.; Elrington, Margaret; Greenwood, Norman N., Journal of the Chemical Society, Dalton Transactions, 1985, p. 2407 - 2416

  摘要：

  DOI：

文献信息

• Polyhedral ruthenaborane chemistry. Approaches to encapsulated boron cores. The isolation and characterisation of the partially encapsulated isocloso 10-vertex {RuB9} cluster compound [(PPh3)RuB9H9{RuCl2(PPh3)2}2]
  作者：Young-Hee Kim、Lawrence Barton、Nigam P. Rath、John D. Kennedy

  DOI：10.1016/j.inoche.2004.09.006

  日期：2005.2

  [RuCl2(Ph-3)(2)] with [arachno-B9H14]- gives [(PPh3)RuB9H9RuCl2(PPh3)(2)}(2)], which has an isocloso 10-vertex RuB(9)j}core geometry that is partially encapsulated by exo-polyhedral RuCl2(PPh3)(2)} units that cap RuB2} triangular faces with one RuClRu} and two RuHB} bridges each. The structure engenders focus on the several new compound classes emerging in polyhedral boron-containing cluster chemistry. (C) 2004 Elsevier B.V. All rights reserved.