(E)-1-ferrocenyl-2-(2,4,6-tri-tert-butylphenyl)diphosphene | 173602-83-0

• 英文名称: (E)-1-ferrocenyl-2-(2,4,6-tri-tert-butylphenyl)diphosphene
• CAS: 173602-83-0
• 化学式: C₂₈H₃₈FeP₂
• 分子量: 492.404
• InChiKey: VTVWSTPEJFMYBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (E)-1-ferrocenyl-2-(2,4,6-tri-tert-butylphenyl)diphosphene 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, Spectroscopic Properties, and Reactivity of Ferrocenyl(2,4,6-tri-tert-butylphenyl)diphosphene

  摘要：

  A ferrocenyl-substituted diphosphene has been synthesized and characterized, which seems to represent a borderline case concerning the dimerization of such species. Thus, the tetraphosphetane formed by dimerization readily undergoes cycloreversion to the initial diphosphene upon heating in xylene solution.

  DOI：

  10.1021/om950384f
• 作为产物：
  描述：

  二氯膦二茂铁 、 P-trimethylsilyl-2,4-6-tri-tert-butylphenylphosphine 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 以82%的产率得到(E)-1-ferrocenyl-2-(2,4,6-tri-tert-butylphenyl)diphosphene
  参考文献：
  名称：

  Synthesis, Spectroscopic Properties, and Reactivity of Ferrocenyl(2,4,6-tri-tert-butylphenyl)diphosphene

  摘要：

  A ferrocenyl-substituted diphosphene has been synthesized and characterized, which seems to represent a borderline case concerning the dimerization of such species. Thus, the tetraphosphetane formed by dimerization readily undergoes cycloreversion to the initial diphosphene upon heating in xylene solution.

  DOI：

  10.1021/om950384f