[Ru2(μ-H)(μ-η(3)-PhC=CHC(O)N(C2H5)2)(CO)6] | 198982-12-6

• 英文名称: [Ru2(μ-H)(μ-η(3)-PhC=CHC(O)N(C2H5)2)(CO)6]
• CAS: 198982-12-6
• 化学式: C₁₉H₁₇NO₇Ru₂
• 分子量: 573.486
• InChiKey: WPWGBNNIPPHYJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru2(μ-H)(μ-η(3)-PhC=CHC(O)N(C2H5)2)(CO)6] 以 not given 为溶剂， 生成 [Ru4(μ-H)2(μ-η(3)-PhC=CHC(O)N(C2H5)2)2(CO)10]
  参考文献：
  名称：

  Binuclear and tetranuclear complexes prepared by reactions of dodecacarbonyltriruthenium with the N-substituted cinnamic acid amides. Crystals and molecular structures of [Ru2(μ-H)(μ-η3-PhCCHC(O)N(CH2)4)(CO)6] and [Ru4(μ3-H)2(μ-η3-PhCCHC(O)N(CH2)4)2(CO)10]

  摘要：

  The thermal reactions of Ru-3(CO)(12) with the N-substituted cinnamic acid amides PhCH=CHCONRR' (1) in hydrocarbons yield the binuclear and tetranuclear complexes, [Ru-2(mu-H)(mu-eta(3)-PhC=CHC(O)NRR') (CO)(6)] (2) and [Ru-4(mu(3)-H)(2)(mu-eta(3)-PhC=CHC(O) NRR')(CO)(10)] (3), involving five-membered oxaruthenacycles eta(3) coordinated by the second ruthenium atom. The structures of the complexes were determined by single crystal X-ray diffraction studies. On heating in hydrocarbons, complexes 2 are converted into clusters 3. The reverse transformation occurs on treatment of complexes 3 by methylene chloride. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00173-x
• 作为产物：
  描述：

  [Ru4(μ-H)2(μ-η(3)-PhC=CHC(O)N(C2H5)2)2(CO)10] 以 二氯甲烷 为溶剂， 生成 [Ru2(μ-H)(μ-η(3)-PhC=CHC(O)N(C2H5)2)(CO)6]
  参考文献：
  名称：

  Binuclear and tetranuclear complexes prepared by reactions of dodecacarbonyltriruthenium with the N-substituted cinnamic acid amides. Crystals and molecular structures of [Ru2(μ-H)(μ-η3-PhCCHC(O)N(CH2)4)(CO)6] and [Ru4(μ3-H)2(μ-η3-PhCCHC(O)N(CH2)4)2(CO)10]

  摘要：

  The thermal reactions of Ru-3(CO)(12) with the N-substituted cinnamic acid amides PhCH=CHCONRR' (1) in hydrocarbons yield the binuclear and tetranuclear complexes, [Ru-2(mu-H)(mu-eta(3)-PhC=CHC(O)NRR') (CO)(6)] (2) and [Ru-4(mu(3)-H)(2)(mu-eta(3)-PhC=CHC(O) NRR')(CO)(10)] (3), involving five-membered oxaruthenacycles eta(3) coordinated by the second ruthenium atom. The structures of the complexes were determined by single crystal X-ray diffraction studies. On heating in hydrocarbons, complexes 2 are converted into clusters 3. The reverse transformation occurs on treatment of complexes 3 by methylene chloride. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00173-x

文献信息

• Reactions of Ru3(CO)12 with cinnamic acid amides
  作者：L. V. Rybin、N. A. Shtel'tser、M. I. Rybinskaya、P. V. Petrovskii

  DOI：10.1007/bf02495946

  日期：1997.7