[Cu(N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,2-diamine)]BF4 | 158363-38-3

• 英文名称: [Cu(N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,2-diamine)]BF4
• 英文别名: [Cu(N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-diamine)]BF4
• CAS: 158363-38-3
• 化学式: BF₄*C₃₉H₃₆N₂P₂*Cu
• 分子量: 745.026
• InChiKey: NUFRACZDZLVRTK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Cu(N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,2-diamine)]BF4 、 四丁基高氯酸铵 以 1,2-二氯乙烷 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  [Cu(H₂dppd)(η¹-OClO₃)]ClO₄: the first crystallographically characterized phosphine complex of copper(II){H₂dppd =N,N′-bis[2-(diphenylphosphino)phenyl]propane-1,3-diamine}

  摘要：

  The title complex 2, easily obtained by controlled potential oxidation of the copper(I) precursor [Cu(H(2)dppd)]BF4 1, in perchlorate medium, crystallizes as a C6H6 monosolvate from dichloroethane-benzene, (2a), or as a CH2Cl2 hemisolvate from dichloromethane-toluene (2b), to give dark-red crystals which have been structurally characterized by X-ray crystallography.

  DOI：

  10.1039/cc9960000433
• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 N,N'-bis<2-(diphenylphosphino)phenyl>propane-1,3-diamine 以 二氯甲烷 为溶剂， 生成 [Cu(N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,2-diamine)]BF4
  参考文献：
  名称：

  Stabilization of copper(I) by phosphinoamines

  摘要：

  Tetradentate phosphinoamines N,N'-bis[2-(diphenylphosphino)phenyl]ethane-1,2-diamine (H-2dpen) and N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-diamine stabilize copper(I) complexes either by ligand-exchange reactions from labile [Cu(I)(MeCN)4]+ or ligand-promoted reduction of a Cu(III)Cl2.2H2O precursor; the structure of one of the products, [Cu(H-2dpen)]BF4, has been determined.

  DOI：

  10.1039/dt9940002471