| 371783-22-1

• CAS: 371783-22-1
• 化学式: BF₄*C₂₈H₂₇FeNO₂P
• 分子量: 583.153
• InChiKey: VYFZWLCHFVPQAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氟硼酸-二乙醚络合物 、 (η4-C5H5Bu)Fe(CO)2(PPh2Py) 以 四氢呋喃 为溶剂， 以33%的产率得到
  参考文献：
  名称：

  ABSTRACTION OFENDO-H OF (η⁴-BuC₅H₅)Fe(CO)₂PPh_3−nPy_n(n = 1 AND 2)USING LEWIS ACIDS

  摘要：

  Dropwise addition of an excess amount of HBF4. OEt2 through a pressure equalizing funnel to (eta (4)-BuC5H5) Fe(CO)(2)PPh3-nPyn resulted in [(eta (5) -BuC5H4)Fe(CO)(2)PPh3-n Py-n(+)][BF4-]. The smooth abstraction of the endo-H atom of (eta (4)-BuC5H5)Fe(CO)(2)PPh3-nPyn is a result of the hydridic nature of this hydrogen. HBF4. OEt2 which worked better than an other Lewis acid, Ph3C+PF6-, because the H-2 produced in the course of the reaction could be removed, whereas Ph3CH remains in the solution along with a catonic species which is partially soluble in THF. The hydride abstraction of the neutral complexes was followed spectroscopically.

  DOI：

  10.1081/sim-100104846