| 165814-11-9

• CAS: 165814-11-9
• 化学式: C₂₂H₁₂MoN₆O₄
• 分子量: 520.315
• InChiKey: QKFMBCZFETZTCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of the mononuclear Mo(CO)4(L) [L = 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt)] complexes and the chelating action of the Mo(CO)4(tpt) derivative towards M(hfac)2 (M = Mn, Fe, Co, Ni, Cu Zn; hfac = hexafluoracetylacetonate ion)

  摘要：

  The novel mononuclear tetracarbonyl complexes Mo(CO)(4)(L), where L is 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt), have been synthesized and characterized. The ligands dppt and tpt seem to be coordinated to the metal centre via a pyridyl nitrogen and a triazine nitrogen. The tpt complex Mo(CO)(4)(tpt) is effective as a bidentate chelating system toward the acidic M(hfac)(2) (M = Mn, Fe, Co, Ni, Cu, Zn) species producing the bimetallic (CO)(4)Mo(tpt)M(hfac)(2) compounds. In these Mo-tpt-M products the ligating Mo(CO)(4)(tpt) complex is coordinated in an unusual mode involving only pyridyl nitrogen atoms. The new substances were characterized by IR, H-1 NMR, electronic spectroscopy, electrochemical and magnetic moment measurements.

  DOI：

  10.1016/0277-5387(94)00436-i
• 作为产物：
  描述：

  3,5,6-三-2-吡啶基-1,2,4-三嗪 、 cis-tetracarbonylbis(piperidine)molybdenum 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis of the mononuclear Mo(CO)4(L) [L = 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt)] complexes and the chelating action of the Mo(CO)4(tpt) derivative towards M(hfac)2 (M = Mn, Fe, Co, Ni, Cu Zn; hfac = hexafluoracetylacetonate ion)

  摘要：

  The novel mononuclear tetracarbonyl complexes Mo(CO)(4)(L), where L is 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt), have been synthesized and characterized. The ligands dppt and tpt seem to be coordinated to the metal centre via a pyridyl nitrogen and a triazine nitrogen. The tpt complex Mo(CO)(4)(tpt) is effective as a bidentate chelating system toward the acidic M(hfac)(2) (M = Mn, Fe, Co, Ni, Cu, Zn) species producing the bimetallic (CO)(4)Mo(tpt)M(hfac)(2) compounds. In these Mo-tpt-M products the ligating Mo(CO)(4)(tpt) complex is coordinated in an unusual mode involving only pyridyl nitrogen atoms. The new substances were characterized by IR, H-1 NMR, electronic spectroscopy, electrochemical and magnetic moment measurements.

  DOI：

  10.1016/0277-5387(94)00436-i