lithium hexafluororhodate(V) | 226388-39-2

• 英文名称: lithium hexafluororhodate(V)
• CAS: 226388-39-2
• 化学式: F₆Rh*Li
• 分子量: 223.837
• InChiKey: YFWKQEOHMDFAOH-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  lithium hexafluororhodate(V) 、 lithium iodide 以 氢氟酸 为溶剂， 生成
  参考文献：
  名称：

  Einkristalluntersuchungen an LiMF6 (M = Rh, Ir), Li2RhF6 und K2IrF6

  摘要：

  LiRhF6, LiIrF6, Li2RhF6, and K2IrF6 were obtained again, but for the first time investigated by single crystal X-ray methods. Rubyred LiRhF6 and yellow LiIrF6 crystallize isostructural in the trigonal space group R(3) over bar - C-3i(2) (Nr.148) with the lattice parameters LiRhF6: a 502.018(7) pm, c = 1355.88(3) pm, Z = 3 and d(Rh-F) = 185.5(1) pm; LiIrF6: a = 506.148(4) pm, c = 1362.60(2) pm, Z = 3, d(Ir-F) = 187.5(3) pm (LiSbF6-Typ). Yellow Li2RhF6 14 crystallizes tetragonal in the space group P4(2)/mnm - D-4h(14) (Nr.136) with a = 463.880(8) pm, c = 905.57(2) pm, Z = 2 and d(Rh-F) = 190.3(4)-191.4(3) pm (Trirutil-Typ). Yellow K2IrF6 3 crystallizes trigonal in the space group P(3$) over bar m1 - D-3d(3) (Nr.164) with a = 578.88(7) pm, c = 465.06(5) pm, Z = 1 and d(Ir-F) 194.0(6) pm, isotypic with K2GeF6.

  DOI：

  10.1002/1521-3749(200201)628:1<133::aid-zaac133>3.0.co;2-s
• 作为产物：
  描述：

  rhodium(V) fluoride 、 lithium fluoride 以 氢氟酸 为溶剂， 生成 lithium hexafluororhodate(V)
  参考文献：
  名称：

  Einkristalluntersuchungen an LiMF6 (M = Rh, Ir), Li2RhF6 und K2IrF6

  摘要：

  LiRhF6, LiIrF6, Li2RhF6, and K2IrF6 were obtained again, but for the first time investigated by single crystal X-ray methods. Rubyred LiRhF6 and yellow LiIrF6 crystallize isostructural in the trigonal space group R(3) over bar - C-3i(2) (Nr.148) with the lattice parameters LiRhF6: a 502.018(7) pm, c = 1355.88(3) pm, Z = 3 and d(Rh-F) = 185.5(1) pm; LiIrF6: a = 506.148(4) pm, c = 1362.60(2) pm, Z = 3, d(Ir-F) = 187.5(3) pm (LiSbF6-Typ). Yellow Li2RhF6 14 crystallizes tetragonal in the space group P4(2)/mnm - D-4h(14) (Nr.136) with a = 463.880(8) pm, c = 905.57(2) pm, Z = 2 and d(Rh-F) = 190.3(4)-191.4(3) pm (Trirutil-Typ). Yellow K2IrF6 3 crystallizes trigonal in the space group P(3$) over bar m1 - D-3d(3) (Nr.164) with a = 578.88(7) pm, c = 465.06(5) pm, Z = 1 and d(Ir-F) 194.0(6) pm, isotypic with K2GeF6.

  DOI：

  10.1002/1521-3749(200201)628:1<133::aid-zaac133>3.0.co;2-s