(C5(CH3)5)Ru(η5-CH(C6H5)C(CH3)CHCHCH2) | 287380-13-6

• 英文名称: (C5(CH3)5)Ru(η5-CH(C6H5)C(CH3)CHCHCH2)
• CAS: 287380-13-6
• 化学式: C₂₂H₂₈Ru
• 分子量: 393.534
• InChiKey: ZYUAVEGRGZMZIY-SJUZGPMKSA-N

反应信息

• 作为产物：
  描述：

  1-苯基-1-丙炔 、 (η5-C5Me5)RuBr2(η3-allyl) 在 Zn 作用下， 以 四氢呋喃 为溶剂， 生成 (C5(CH3)5)Ru(η5-CH(C6H5)C(CH3)CHCHCH2)
  参考文献：
  名称：

  Allyl/Alkyne Coupling Reactions Mediated by Neutral Ruthenium(II). Isolation and Characterization of Ruthenium(II) η³-Allyl η²-Alkyne Complexes

  摘要：

  In contrast to the cyclization products obtained from allyl/alkyne coupling reactions in the isostructural cationic series, neutral complexes of the form (C5Me5)Ru(eta(3)-allyl)(eta(2)-alkyne) react to give acyclic eta(5)-pentadienyl complexes in high yield.

  DOI：

  10.1021/om000275n