CpZr[OC9H5NCHNC6H3Cl2]Cl2 | 1272520-29-2

• 英文名称: CpZr[OC9H5NCHNC6H3Cl2]Cl2
• CAS: 1272520-29-2
• 化学式: C₂₁H₁₄Cl₄N₂OZr
• 分子量: 543.391
• InChiKey: YOBRVVPPCWENDU-PHIQMRKCSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cyclopentadienylzirconium trichloride 、 2-((2,6-dichlorophenylimino)methyl)quinolin-8-ol 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以61%的产率得到CpZr[OC9H5NCHNC6H3Cl2]Cl2
  参考文献：
  名称：

  Syntheses, Characterization, and Ethylene Polymerization of Half-Sandwich Zirconium Complexes with Tridentate Imino−Quinolinol Ligands

  摘要：

  A series of half-sandwich zirconium complexes with imino-quinolinol ligands have been synthesized and characterized. The catalytic behaviors of these complexes toward ethylene polymerization were investigated in the presence of methylaluminoxane (MAO) as a cocatalyst. The catalytic behaviors were highly affected by the substituent in both cyclopentadienyl and imino-quinolinol ligands. The Cp analogue complexes CpZr[ONNR]Cl-2 (1a-e) exhibited high activities up to 1.34 x 10(7) g of PE (mol of Zr)(-1) h(-1), whereas the Cp* analogue complexes Cp*Zr[ONNR]Cl-2 (2a-e) also showed moderate activities for ethylene polymerization.

  DOI：

  10.1021/om101059v