| 886987-30-0

• CAS: 886987-30-0
• 化学式: C₅₆H₅₄ClO₂P₃Ru
• 分子量: 988.488
• InChiKey: AUCXZGOWDGCLMU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 4,6-di-tert-butylresorcinolbis(diisopropylphosphinite) 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Ruthenium PCP–bis(phosphinite) pincer complexes

  摘要：

  The reactions of [RuHCl(CO)(PPh3)(3)] with resorcinol bis(phosphinite) pincer ligands lead to complexes of the general formula [RuCl(PCP)(CO)(PPh3)]; the crystal structure of one example has been determined. The structures of the bulky resorcinol 2-methyl4,6-di-tert-butyl resorcinol and its mono-diisopropylphosphinite derivative were also determined. Reactions of [RuCl2(PPh3)(3)] with resorcinot bis(phosphinite) ligands yield complexes of the type [RuCl(PCP)(PPh3)], while the reaction of C6H-2-Me-4,6-'Bu-2-1,3-(OPPh2) with [RuHCl(CO)(PPh3)(3)] provides a PCP-pincer complex in which the ligand has undergone 2-methyl C-H activation. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.07.050