dichlorido-2,6-bis(1-hydroxy-1-o-tolyl-ethyl-η2-O,O)pyridinecopper(II) | 1352662-43-1

• 英文名称: dichlorido-2,6-bis(1-hydroxy-1-o-tolyl-ethyl-η2-O,O)pyridinecopper(II)
• 英文别名: [CuCl2(pydotH2)]
• CAS: 1352662-43-1
• 化学式: C₂₃H₂₅Cl₂CuNO₂
• 分子量: 481.909
• InChiKey: ZLTXSUZALHSSQV-GQOINVLUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2,6-bis(1-hydroxy-1-(o-tolyl)ethyl)pyridine 以 丙酮 为溶剂， 以80%的产率得到dichlorido-2,6-bis(1-hydroxy-1-o-tolyl-ethyl-η2-O,O)pyridinecopper(II)
  参考文献：
  名称：

  Oxido-pincer complexes of copper(II) – An EXAFS and EPR study of mono- and binuclear [(pydotH2)CuCl2]n (n=1 or 2)

  摘要：

  The oxido-pincer ligand pydotH(2) (2,6-bis(1-hydroxy-1-o-tolyl-ethyl-eta O-2,O')pyridine) forms two different Cu-II containing complexes when prepared from anhydrous CuCl2. A combination of EPR spectroscopy and EXAFS allowed to structurally characterise the light-green dimer of the formula [(pydotH(2))CuCl(mu-Cl)(2)ClCu(pydotH(2))] and the penta-coordinate olive-green monomer [(pydotH(2))CuCl2]. The molecular entities imply that the ligand remains protonated upon coordination. When dissolved in DMF both compounds form monomeric species [(pydotH(2))CuCl2(DMF)] which could be characterised in detail by EPR. UV-Vis/NIR spectroscopy and electrochemical measurements. The assignments were supported by comparison with Cu-II complexes of the related ligands 2,6-bis(hydroxymethyl)pyridine (pydimH(2)) and 2,6-bis(1-hydroxy-1-methyl)pyridine (pydiPH(2)). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.10.023