| 1309578-23-1

• CAS: 1309578-23-1
• 化学式: C₄₁H₄₈N₂O₂PRh
• 分子量: 734.724
• InChiKey: VLLGNJBWPYOQAS-CUWITMTGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 (C6H3i-Pr2)NC(Me)CH2PPh2(NC6H3i-Pr2) 在 n-butyllithium 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Rhodium carbonyl complexes of bulky, anionic nitrogen-based ligands: A comparison of donating ability

  摘要：

  Phosphinimine-imine ((C(6)H(3)i-Pr-2)NC(Me)CH2PPh2(NC(6)H(3)i-Pr-2))Rh(CO)(2) - (1) and beta-diketiminate CH (C(Me)(Ni-Pr2C6H3))(2)Rh(CO)(2) - (2) rhodium dicarbonyl complexes were prepared as to elucidate any difference among these anionic, nitrogen-based ligands regarding donating ability to the rhodium center. Utilizing infrared spectroscopy and single crystal structural comparisons, differences in electron density donation by the ligands to the rhodium center were not observed. The carbonyl stretching frequencies of the aforementioned rhodium complexes were nu(CO) = 2055, 1987 and 2055, 1988 for the phosphinimine-imine (1) and beta-diketiminate (2) respectively. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.03.036