(2-hydroxyethylthio)porphyrazinato magnesium | 340027-81-8

• 英文名称: (2-hydroxyethylthio)porphyrazinato magnesium
• CAS: 340027-81-8
• 化学式: C₃₂H₄₂MgN₈O₈S₈
• 分子量: 947.567
• InChiKey: SGPDMGFFWRXSGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  喹啉-3-羧酸 、 (2-hydroxyethylthio)porphyrazinato magnesium 在 吡啶 、 对甲苯磺酸 、 N,N'-二环己基碳二亚胺 作用下， 以28%的产率得到{2,3,7,8,12,13,17,18-octakis[2′-(3-quinolinecarboxy)-ethylthio]porphyrazinato N²¹N²²N²³N²⁴}magnesium
  参考文献：
  名称：

  Synthesis, spectral and photophysical investigation of porphyrazines with eight 3-quinolinecarboxy esters

  摘要：

  In this study, the syntheses and characterization of [2,3,7,8,12,13,17,18-octakis [2-(3-quinolincarboxy)ethylhio] porphyrazinato (NNNN24)-N-21-N-22-N-23] magnesium(II), quaternized [2,3,7,8,12,13,17,18-octakis [2-(3-quinolincarboxy)ethylhio] porpyrazinato (NNNN24)-N-21-N-22-N-23] magnesium(II), [2,3,7,8,12,13,17,18-octakis[2-(3-quinolinecarboxy)-ethylthio]21H23H (NNNN24)-N-21-N-22-N-23 porphyrazine and [2,3,7,8,12,13,17,18-octakis[2-(3-quinolinecarboxy)-ethylthio]porphyrazinato (NNNN24)-N-21-N-22-N-23} zinc are described. The new compounds have been characterized by elemental analysis, FT-IR, H-1-NMR, and mass spectra. General trends are described for fluorescence quantum yields of these compounds in dimethylsulfoxide (DMSO). In this study, the effects quaternization of the substituents on the photophysical and spectroscopic properties are also reported.

  DOI：

  10.1080/00958972.2013.867035