[Ru3(μ-1,2-bis(diphenylphosphino)methane)(CO)9(P(i-Pr)3)] | 465500-54-3

• 英文名称: [Ru3(μ-1,2-bis(diphenylphosphino)methane)(CO)9(P(i-Pr)3)]
• CAS: 465500-54-3
• 化学式: C₄₃H₄₃O₉P₃Ru₃
• 分子量: 1099.94
• InChiKey: QHLXBAYTYKOPFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三异丙基膦 、 Ru3(CO)10(μ-bis(diphenylphosphino)methane) 以 四氢呋喃 为溶剂， 以63%的产率得到[Ru3(μ-1,2-bis(diphenylphosphino)methane)(CO)9(P(i-Pr)3)]
  参考文献：
  名称：

  Phosphine substituted Ru3(μ-dppm)(CO)10: structural trends within [Ru3(μ-dppm)(PR3)(CO)9] (R=Et, Ph, Cy and Pri)

  摘要：

  The complexes [Ru-3(mu-dppm)(PR3)(CO)(9)] (R=Et, Ph, Cy, Pr'} were prepared from [Ru-3(mu-dppm)(CO)(10)] by simple phosphine substitution reactions at room temperature and their structures determined by single crystal X-ray studies. Variations in the Ru-Ru bond adjacent to the phosphine ligand suggest the enhanced reactivity of [Ru-3(mu-dppm)(CO)(10)] over the parent carbonyl [Ru-3(CO)(12)] to be consequent on the inability of [Ru-3(mu-dppm)(CO)(10)] to effectively relieve steric congestion imposed by the presence of the bulky, bidentate dppm ligand. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01567-x