trichlorobis(tetramethylethylenediamine)dicopper(II) hexafluorophosphate | 849906-08-7

• 英文名称: trichlorobis(tetramethylethylenediamine)dicopper(II) hexafluorophosphate
• 英文别名: trichlorobis(tetramethylethylenediamine)dicopper(II) hexafluorophosphate C12H32Cl3Cu2N4(1+)*F6P(1-), room temperature, tetragonal
• CAS: 849906-08-7
• 化学式: C₁₂H₃₂Cl₃Cu₂N₄*F₆P
• 分子量: 610.828
• InChiKey: BHAMGXQIWQQSFQ-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 copper (II) dichloro(N,N,N',N'-tetramethylethylenediamine) 以 丙酮 为溶剂， 以52.5%的产率得到trichlorobis(tetramethylethylenediamine)dicopper(II) hexafluorophosphate
  参考文献：
  名称：

  Copper(II) PMDTA and copper(II) TMEDA complexes: precursors for the synthesis of dinuclear dicationic copper(II) complexes

  摘要：

  Copper(II) cations coordinated with PMDTA (pentamethyldiethylenetriamine) and TMEDA (tetramethylethylenediamine) possess a high synthetic potential. The synthesis of these cations was carried out by metathesis reactions with silver salts. The cationic copper(II) complexes, [Cu(PMDTA)(MeCO)Cl](+), [Cu(PMDTA)(H2O)Cl](+), [Cu(PMDTA)(DMF)](+), [Cu(PMDTA)Cl](+), [Cu(PMDTA)OAc](+), [Cu(PMDTA)(MeCN)(2)](2+), [Cu-2(TMEDA)(2)Cl-3](+) and [Cu(TMEDA)(MeCN)(3)](2+) were synthesised as PF6 salts, crystallised and characterised by single-crystal X-ray diffraction. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.11.002