| 452899-46-6

• CAS: 452899-46-6
• 化学式: C₇H₈*C₂₉H₄₁FGeN₂S
• 分子量: 633.453
• InChiKey: GISJQIHBBBEQFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ge(CH{(CH3)CN-2,6-iPr2C6H3}2)Cl 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Structures of [{HC(CMeNAr)₂}Ge(S)X] (Ar = 2,6-iPr₂C₆H₃, X = F, Cl, Me):  Structurally Characterized Examples with a Formal Double Bond between Group 14 and 16 Elements Bearing a Halide

  摘要：

  Treatment of [{HC(CMeNAr)2}GeX] (Ar = 2,6-iPr2C6H3, X = Cl (1), F (2)), with elemental sulfur at room temperature smoothly afforded the [{HC(CMeNAr)2}Ge(S)X] (X = Cl (3), F (4)). Compound 4 can also be obtained from 3 with the fluorination reagent Me3SnF. Reaction of 3 with MeLi led to the formation of [{HC(CMeNAr)2}Ge(S)Me] (5). Single-crystal X-ray structural analyses indicate compounds 3-5 are monomeric. The germanium centers adopt four coordinated sites and reside in distorted tetrahedral environment. Compounds 3 and 4 are structurally characterized examples with a formal double bond between group 14 and 16 elements bearing a halide.

  DOI：

  10.1021/ja017645z