dichloro[1,4,7,10-tetraaza-5,6,11,12-tetramethyl-4,6,10,12-tetraene-2,3:8,9-dibenzylcyclodidecane]cobalt(II) | 872679-10-2

• 英文名称: dichloro[1,4,7,10-tetraaza-5,6,11,12-tetramethyl-4,6,10,12-tetraene-2,3:8,9-dibenzylcyclodidecane]cobalt(II)
• CAS: 872679-10-2
• 化学式: C₂₀H₂₀Cl₂CoN₄
• 分子量: 446.305
• InChiKey: UZHMTCCKBZOSGH-MEZAJFLCSA-L

反应信息

• 作为产物：
  描述：

  邻苯二胺 、 cobalt(II) chloride hexahydrate 、 2,3-丁二酮 以 甲醇 为溶剂， 以56%的产率得到dichloro[1,4,7,10-tetraaza-5,6,11,12-tetramethyl-4,6,10,12-tetraene-2,3:8,9-dibenzylcyclodidecane]cobalt(II)
  参考文献：
  名称：

  Metal Ion Directed Synthesis of 12 and 14-Membered Tetraaza Macrocyclic Complexes and their Physico-Chemical Studies

  摘要：

  The template condensation reaction of o-phenylenediamine with 2,3-butanedione or 2,4-pentanedione resulted in the formation of new series of 12 and 14-membered tetraaza macrocyclic complexes: [ML1 Cl-2], [ML2 Cl-2] [M=Co(II), Ni(II) and Zn(II)]; [CuL1] Cl-2 and [CuL2] Cl-2. The formation of the macrocyclic framework and the overall geometry of the complexes have been characterized by elemental analyses, FT-IR, (HNMR)-H-1, UV-Visible, magnetic susceptibility and conductivity measurements. The copper( II) complexes exhibit square planar geometry, whereas an octahedral geometry is suggested for all other complexes.

  DOI：

  10.1081/sim-200067064