[Fe(O-acrylamide)6][(μ-oxo)-bis[trichloroferrate]] | 1005416-44-3

• 英文名称: [Fe(O-acrylamide)6][(μ-oxo)-bis[trichloroferrate]]
• CAS: 1005416-44-3
• 化学式: C₁₈H₃₀FeN₆O₆*Cl₆Fe₂O
• 分子量: 822.731
• InChiKey: LMJIEMRZGAUWOK-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三氯化铁 、 丙烯酰胺 、 iron(II) chloride 以 硝基甲烷 为溶剂， 以58%的产率得到[Fe(O-acrylamide)6][(μ-oxo)-bis[trichloroferrate]]
  参考文献：
  名称：

  Coordination chemistry of acrylamide 6: Formation and structural characterization of [Fe(O-OC(NH2)CHCH2)6][Fe2OCl6]

  摘要：

  The new acrylamide iron(II)/iron(III) complex [Fe(O-OC(NH2)CH=CH2)(6)][Fe2OCl6] (1) was obtained by the reaction of a mixture of anhydrous FeCl2 and anhydrous FeCl3 with acrylamide (molar ratio 1:2:6) in 98% pure commercial nitromethane under nitrogen atmosphere. According to an X-ray structural analysis, the acrylamide ligands in the cation are coordinated via the amide-oxygen atoms. The formation of the (mu-oxo)bis[trichloroferrate(III)](2-) anion presumably resulted from partial hydrolysis of FeCl3 or [FeCl4](-) by small amounts of water in the nitromethane and/or by the nitromethane itself. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.06.012