tetrachloro(9,10:20,21-dibenzo-1,4,7,12,15,18-hexaazacyclobicosane-1,8,11,18-tetraene)dinickel(II) | 172665-20-2

• 英文名称: tetrachloro(9,10:20,21-dibenzo-1,4,7,12,15,18-hexaazacyclobicosane-1,8,11,18-tetraene)dinickel(II)
• CAS: 172665-20-2
• 化学式: C₂₄H₃₀Cl₄N₆Ni₂
• 分子量: 661.734
• InChiKey: YRQPGLSKWOFGSJ-GORPIVTHSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 二乙烯三胺 、 邻苯二甲醛 以 甲醇 为溶剂， 以30%的产率得到tetrachloro(9,10:20,21-dibenzo-1,4,7,12,15,18-hexaazacyclobicosane-1,8,11,18-tetraene)dinickel(II)
  参考文献：
  名称：

  Binuclear N6 22-membered macrocyclic transition metal complexes: synthesis and characterization

  摘要：

  A novel family of tetraiminehexaazamacrocyclic complexes [M(2)LX(4)] (M = Co-II, Ni-II and Zn-II) and [Cu(2)LX(2)](2+) (X = Cl or NO3) has been prepared by the condensation reaction of diethylenetriamine with phthalaldehyde in the presence of metal ions as templates in methanol medium. The complexes have been characterized on the basis of elemental analysis, IR, H-1 NMR, EPR and UV-vis spectroscopic studies, as well as conductivity and magnetic susceptibility data. All the complexes except that of copper, which is square planar, have octahedral structures.

  DOI：

  10.1016/0277-5387(95)00189-y