[(RuCl(CO)(AsPh3)2)2(4,6-diacetylresorcinato)] | 1243263-96-8

• 英文名称: [(RuCl(CO)(AsPh3)2)2(4,6-diacetylresorcinato)]
• CAS: 1243263-96-8
• 化学式: C₈₄H₆₈As₄Cl₂O₆Ru₂
• 分子量: 1746.19
• InChiKey: BOGPOZDPVLEHKI-UHFFFAOYSA-J

计算性质

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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(hydride)(chloride)(carbonyl)(triphenylarsine)3] 、 1,1'-(4,6-二羟基苯)二乙酮 在 triethylamine 作用下， 以 benzene 为溶剂， 生成 [(RuCl(CO)(AsPh3)2)2(4,6-diacetylresorcinato)]
  参考文献：
  名称：

  Studies on the synthesis, spectra, catalytic and antibacterial activities of binuclear ruthenium(II) complexes

  摘要：

  A new series of stable binuclear ruthenium(II) carbonyl complexes of the general formula [{RuX(CO)(EPh3)(2)}(2)L] (where X=H or Cl; E=P or As and L=dibasic tetradentate diacetyl resorcinol (H-2-DAR)) have been synthesised by reacting ruthenium(II) starting complexes [RuHX(CO)(EPh3)(3)] (where X=H or CI; E=P or As) and 4,6-diacetylresorcinol (H-2-DAR) ligand in benzene medium. The structure of the new binuclear ruthenium(II) carbonyl complexes was established using elemental analysis, spectra (FT-IR, UV-vis and H-1 NMR), electrochemical and thermal studies. In these reactions, the 4,6-diacetylresorcinol (H-2-DAR) ligand behaves as a binegative tetradentate chelating ligand coordinating through O,O atoms of both the carbonyl and phenolic C-O groups by replacing a molecule of PPh3/AsPh3 and a hydride ion from the starting complexes. Further, all these complexes were also employed as new catalysts for the oxidation of primary and secondary alcohols in the presence of N-methylmorpholine-N-oxide (NMO) as a more viable co-oxidant. The free ligand and their metal complexes have also been screened for their antibacterial activity against the growth of gram +ve and gram -ve bacterial cultures. (c) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2010.05.019