[Ga(2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)amino]-2-pentene)Cl(tBu)] | 1047678-40-9

• 英文名称: [Ga(2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)amino]-2-pentene)Cl(tBu)]
• 英文别名: [GaCl(DDP)tBu]
• CAS: 1047678-40-9
• 化学式: C₃₃H₅₀ClGaN₂
• 分子量: 579.949
• InChiKey: FVEOCKCZMDQMAK-KSWNCPITSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯代叔丁烷 、 Ga(2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)amino]-2-pentene) 以 正己烷 为溶剂， 以89%的产率得到[Ga(2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)amino]-2-pentene)Cl(tBu)]
  参考文献：
  名称：

  Oxidative Addition of Group 13 and 14 Metal Halides and Alkyls to Ga(DDP) (DDP = Bulky Bisimidinate)

  摘要：

  The oxidative addition of a variety of group 13 and group 14 halides and alkyls R(a)MX to the mono valent group 13 bis-imidinate Ga(DDP) (DDP = 2-((2,6-diisopropyl-phenyl)amino)-4-1(2,6-diisopropylphenyl)iminol-2-pentene) is reported. Accordingly, the insertion of Ga(DIDP) into the Ga-Me bond of GaMe(3) yield in the complexes [{(DDP)GaMe)GaMe(2)] (1) and [{(DDP)GaMe}(2)GaMe] (2), respectively, which show a temperature-dependent equilibrium between 1 at higher temperatures and 2 at lower temperatures. In the case of GaCl(3), the only isolable product is [{(DDP)GaCl}(2)GaCl) (3). The related reaction of SnMe(2)Cl(2) with Ga(DDP) yields the compound [Me(2)Sn(ClGa(DDP)}(2)] (4), whereas SnMe(4) behaves inert. In the case of SiCl(4), only the monoinsertion product [Cl(3)Si(ClGa(DDP)}] (5) was observed. Finally, [(CH(3))(3)C(ClGa(DDP)}] (6) is synthesized by insertion of Ga(DDP) into the C-Cl bond of ClC(CH(3))(3). All new compounds were fully characterized by elemental analysis, NMR-spectroscopy, and single-crystal X-ray diffraction analysis.

  DOI：

  10.1021/ic800690z