Pd(II)Me(2,2′-dipyridyl-N-methylamine)Cl | 1604045-41-1

• 英文名称: Pd(II)Me(2,2′-dipyridyl-N-methylamine)Cl
• 英文别名: Pd^(II)Me(2,2′-dipyridyl-N-methylamine)Cl
• CAS: 1604045-41-1
• 化学式: C₁₂H₁₄ClN₃Pd
• 分子量: 342.136
• InChiKey: CTIYEUICVNOVKQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Pd(II)Me(2,2′-dipyridyl-N-methylamine)Cl 、 四(3,5-二(三氟甲基)苯基)硼酸钠 、 乙腈 以 二氯甲烷 为溶剂， 反应 2.0h， 以69%的产率得到[Pd^(II)Me{2,2′-dipyridyl-N-methylamine}(acetonitrile)]⁺[B(3,5-bis(trifluoromethyl)phenyl)₄]^-
  参考文献：
  名称：

  Reactivity of Bis(pyridyl)-N-alkylaminato Methylpalladium Complexes toward Ethylene: Insights from Experiment and Theory

  摘要：

  A series of novel neutral and cationic methylpalladium complexes bearing N-alkyl-2,2'-dipyridylaldiminato ligands were prepared and characterized. In the presence of ethylene, the cationic complexes were active as dimerization catalysts, producing a mixture of 1- and 2-butenes. A Pd-ethyl pi-ethylene species was identified as the catalyst resting state by low-temperature spectroscopic and DFT studies, which provided insights into the effect of both steric and electronic factors on the observed reactivity.

  DOI：

  10.1021/om5001293
• 作为产物：
  描述：

  2,2'-二吡啶胺 在 potassium hydroxide 作用下， 以 二氯甲烷 、 二甲基亚砜 为溶剂， 反应 36.75h， 生成 Pd(II)Me(2,2′-dipyridyl-N-methylamine)Cl
  参考文献：
  名称：

  Reactivity of Bis(pyridyl)-N-alkylaminato Methylpalladium Complexes toward Ethylene: Insights from Experiment and Theory

  摘要：

  A series of novel neutral and cationic methylpalladium complexes bearing N-alkyl-2,2'-dipyridylaldiminato ligands were prepared and characterized. In the presence of ethylene, the cationic complexes were active as dimerization catalysts, producing a mixture of 1- and 2-butenes. A Pd-ethyl pi-ethylene species was identified as the catalyst resting state by low-temperature spectroscopic and DFT studies, which provided insights into the effect of both steric and electronic factors on the observed reactivity.

  DOI：

  10.1021/om5001293