chloro[5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-p-tolylporphinato]thallium(III) | 1243581-21-6

• 英文名称: chloro[5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-p-tolylporphinato]thallium(III)
• CAS: 1243581-21-6
• 化学式: C₄₈H₃₆ClN₄OTl
• 分子量: 924.676
• InChiKey: WHEZFDBCNXUTCX-HTMHXADGSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5-(4-hydroxymethylphenyl)-10,15,20-tris(4-methylphenyl)porphyrin 在 thallium (III) chloride 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 48.0h， 以78%的产率得到chloro[5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-p-tolylporphinato]thallium(III)
  参考文献：
  名称：

  Synthesis of oligo(p-phenylene)-linked dyads containing free base, zinc(II) or thallium(III) porphyrins for studies in artificial photosynthesis

  摘要：

  A series of (p-phenylene)(n)-linked meso-mesityl-substituted porphyrin dyads (n=2-4) was prepared via Suzuki coupling of zinc(II) and free base porphyrin building blocks. The resulting zinc(II)/free base porphyrin dyads were demetalated. The series of free base porphyrin dimers (n=1-4), four other porphyrin dimers (with p-phenylene, diphenylethyne or diphenylbutadiyne linkers; and aryl or tridec-7-yl meso substituents), and several benchmark monomers were converted to the thallium(III)chloride complexes under mild conditions. The collection of eight Tl(III)Cl/Tl(III)Cl dimers is designed for studies of ground-state hole-transfer processes and comparison with the excited-state energy- and hole-transfer processes of the corresponding Zn(II)/free base dyads. Altogether, 18 new porphyrin arrays and benchmark monomers have been prepared. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.05.059