mer-[Rh(bis(2-diphenylphosphinoethyl)phenyl phosphine)(CO)(OC6H4-p-Me)] | 223929-62-2

• 英文名称: mer-[Rh(bis(2-diphenylphosphinoethyl)phenyl phosphine)(CO)(OC6H4-p-Me)]
• CAS: 223929-62-2
• 化学式: C₄₂H₄₀O₂P₃Rh
• 分子量: 772.605
• InChiKey: WMANCYDGOJBICF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Rh(bis(2-diphenylphosphinoethyl)phenyl phosphine)(CO)]PF6 、 sodium 4-methylphenoxide 以 四氢呋喃 为溶剂， 生成 Rh(bis(2-diphenylphosphinoethyl)phenyl phosphine)(OC₆H₄-p-Me) 、 [Rh(bis(2-diphenylphosphinoethyl)phenyl phosphine)(C(O)OC6H4p-Me)] 、 mer-[Rh(bis(2-diphenylphosphinoethyl)phenyl phosphine)(CO)(OC6H4-p-Me)] 、 mer-[Rh(bis(2-diphenylphosphinoethyl)phenyl phosphine)(CO)(OC6H4-p-Me)]
  参考文献：
  名称：

  IR spectroscopic studies of the reversible equilibria between Rh(I)(triphos) aryloxides, aryloxycarbonyls, and carbonyls

  摘要：

  The complex, [Rh(triphos)CO][PF6] {triphos =bis(2-diphenylphosphinoethyl)phenyl phosphine}, 4, reacts with aryloxides, ArO- {Ar = C6H5, C6H4-p-CH3, C6H4-p-OCH3}. The formation and subsequent chemistry of the resulting aryloxycarbonyl complexes were observed by FTIR spectroscopy. These aryloxycarbonyl complexes are formed and decay via different pathways involving the fac- and mer-isomers of Rh(triphos)(CO)(OAr). Decarbonylation of Rh(triphos)(CO)(OAr) forms Rh(triphos)OAr, {Ar = C6H5 (1), C6H4-p-CH3, (2) C6H4-p-OCH3 (3)}, while elimination of the aryloxide via a different pathway can also reform [Rh(triphos)CO][PF6], 4. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01022-5