(C5(CH3)5)Ru(η5-(CH3CHC(CH3)CHCHCH2)) | 287380-10-3

• 英文名称: (C5(CH3)5)Ru(η5-(CH3CHC(CH3)CHCHCH2))
• CAS: 287380-10-3
• 化学式: C₁₇H₂₆Ru
• 分子量: 331.463
• InChiKey: CONVRPXMEIOMNT-HHEXBWDDSA-N

反应信息

• 作为产物：
  描述：

  (C5(CH3)5)Ru(η3-allyl)(η2-CH3CCCH3) 以 苯 为溶剂， 生成 (C5(CH3)5)Ru(η5-(CH3CHC(CH3)CHCHCH2))
  参考文献：
  名称：

  Allyl/Alkyne Coupling Reactions Mediated by Neutral Ruthenium(II). Isolation and Characterization of Ruthenium(II) η³-Allyl η²-Alkyne Complexes

  摘要：

  In contrast to the cyclization products obtained from allyl/alkyne coupling reactions in the isostructural cationic series, neutral complexes of the form (C5Me5)Ru(eta(3)-allyl)(eta(2)-alkyne) react to give acyclic eta(5)-pentadienyl complexes in high yield.

  DOI：

  10.1021/om000275n