(N->B),(N->B)'-bisdiphenyl-[2,2'-(1,4-piperazinediethoxy)]bisborane | 207730-12-9

• 英文名称: (N->B),(N->B)'-bisdiphenyl-[2,2'-(1,4-piperazinediethoxy)]bisborane
• CAS: 207730-12-9
• 化学式: C₃₂H₃₆B₂N₂O₂
• 分子量: 502.272
• InChiKey: XGFUXLQMQLQHCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 (N->B),(N->B)'-bisdiphenyl-[2,2'-(1,4-piperazinediethoxy)]bisborane 以 甲醇 为溶剂， 生成 bisdiphenylmethoxy-[2,2'-(1,4-piperaziniumdiethoxy)]bisborate
  参考文献：
  名称：

  Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography

  摘要：

  A series of eleven new 2-aminoethyl- and 3-aminopropyl borinate derivatives with a coordinative N --> B bond has been synthesized by condensation reactions between piperidine-as well as piperazine alcohols and diphenylborinic acid. The products obtained are analogous to N-spiro compounds and bicyclic systems and have been characterized by spectroscopic methods and X-ray crystallography. Thereby the N --> B bond and the geometry of this new heterocyclic systems have been studied in more detail. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00636-0
• 作为产物：
  描述：

  1,4-双(2-羟基乙基)哌嗪 、 二苯基二烃基硼酸 以 甲醇 为溶剂， 以78%的产率得到(N->B),(N->B)'-bisdiphenyl-[2,2'-(1,4-piperazinediethoxy)]bisborane
  参考文献：
  名称：

  Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography

  摘要：

  A series of eleven new 2-aminoethyl- and 3-aminopropyl borinate derivatives with a coordinative N --> B bond has been synthesized by condensation reactions between piperidine-as well as piperazine alcohols and diphenylborinic acid. The products obtained are analogous to N-spiro compounds and bicyclic systems and have been characterized by spectroscopic methods and X-ray crystallography. Thereby the N --> B bond and the geometry of this new heterocyclic systems have been studied in more detail. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00636-0