tert-butylamido-tert-butylimido-η5-cyclopentadienyl-η1-indenylvanadium(V) | 233676-99-8

• 英文名称: tert-butylamido-tert-butylimido-η5-cyclopentadienyl-η1-indenylvanadium(V)
• CAS: 233676-99-8
• 化学式: C₂₂H₃₁N₂V
• 分子量: 374.443
• InChiKey: USLRXQLREZFQMP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  indenyllithium 、 chloro-tert-butylamino-tert-butylimino-η5-cyclopentadienyl-vanadium(V) 以 乙醚 为溶剂， 以76%的产率得到tert-butylamido-tert-butylimido-η5-cyclopentadienyl-η1-indenylvanadium(V)
  参考文献：
  名称：

  Indenylvanadium(V)-Verbindungen. Darstellung, Struktur und NMR-spektroskopische Untersuchungen

  摘要：

  Syntheses of the indenylvanadium(V) compounds are described: (C4H9N)-C-t = V(eta(5)-C9H7)Cl-2 (1), (C4H9N)-C-t = V(eta(5)-C9H7)Br-2 (2), (C4H9N)-C-t = V(eta(5)-C9H7)((OC4H9)-C-t)Cl (3), (C4H9N)-C-t = V(eta(1)-C9H7)((OC4H9)-C-t)(2) (4), (C4H9N)-C-t = V(eta(1)- C9H7)(2)((OC4H9)-C-t) (5), (C4H9N)-C-t = V(eta(1)-C9H7)(eta(5)-C5H5). ((OC4H9)-C-t) (6), (C4H9N)-C-t = V(eta(1)-C9H7)(eta(5)-C5H5)((NHC4H9)-C-t) (7). All compounds were totally characterized by spectroscopic methods (MS; H-1, C-13, V-51 NMR), 3 by single crystal X-ray diffraction. For 6 the presence of the diastereomeres RR/SS and RS/SR was shown by NMR spectroscopy. The chlorovanadate (IV) complex [(NH3C4H9)-C-t](2)(+)[((C4H9N)-C-t)(7)V-7, (mu-Cl)(14)Cl-2](2-) has been obtained by decomposition of 1 in solution; the crystal structure indicates a wheel structure with hydrogen bonds between the tert-butylammonium cations and the complex anion.

  DOI：

  10.1002/(sici)1521-3749(199906)625:6<901::aid-zaac901>3.0.co;2-6