| 211059-46-0

• CAS: 211059-46-0
• 化学式: C₂₇H₂₃FeO₂P
• 分子量: 466.299
• InChiKey: PNRYLTLMNNPSOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 trimethylamine-N-oxide dihydrate 以 二氯甲烷 为溶剂， 以54%的产率得到
  参考文献：
  名称：

  Insertion of a Water Oxygen Atom into a Phosphorus−Metal Bond:  From a P-Coordinated (Diphenylphosphino)alkyne to a Coordinated η²(O,C)-Vinyldiphenylphosphine Oxide^†

  摘要：

  The reaction of [(Fp)Ph2PC=CR][BF4] (Fp = (C5H5)Fe(CO)(2); R = H (1), Me (2), tBu (3), Ph (4), Tol (5)) with (CH3)(3)NO . 2H(2)O. (6) was studied, and the new complexes [CpFe(CO)(eta(2)(O,C)-Ph2P(O)CH=CR)] (R = Ph (7), Tol (8)) were isolated. Compound 8 was characterized by X-ray diffraction. An isotopic labeling study showed that the oxygen atom bonded to phosphorus came from a water molecule.

  DOI：

  10.1021/om9801610