| 260995-55-9

• CAS: 260995-55-9
• 化学式: C₂₆H₄₄FeSi₅
• 分子量: 552.91
• InChiKey: UUIBYRRLSWCQAK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1-(chloromercuri)ferrocene 、 在 n-BuLi 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, Spectroscopy, Electrochemical Characterization, and Nonlinear Optical Properties of Ferrocenyloligosilanes:  FcSi_nMe_2n(C₆H₅) (n = 1−6) and FcSi₂Me₄(C₆H₄-X) (X = m-CF₃, p-Cl, p-Br, p-OMe, p-NMe₂, p-CHC(CN)₂)

  摘要：

  New ferrocenyloligosilylene aryl complexes have been synthesized, FcSi(n)Me(2n)C(6)H(5) (n = 1-6) and FcSi(2)Me(4){C6H4-X) (X = m-CF3. p-Cl, p-Br, p-OMe, p-NMe2, p-CH=C(CN)(2)). The complexes have been evaluated with respect to their electrochemical redox and NLO hyperpolarizability properties. All complexes possess oxidation potentials that reflect, systematically but weakly, the various substituents on the aryl group, thereby indicating an aryl-ferrocenyl interaction via the silicon chains. However, hyperpolarizabilities of the complexes are generally similar to those of the corresponding substituted benzenes, with the exception of the most electron-withdrawing substituents, p-Cl and p-CH=C(CN)(2).

  DOI：

  10.1021/om990733w