[(η³-CH₂(C₄H₂O)CO₂CH₃)Pd(PCy₃)₂](triflate) | 1392235-36-7

• 英文名称: [(η³-CH₂(C₄H₂O)CO₂CH₃)Pd(PCy₃)₂](triflate)
• 英文别名: [(η³-CH₂(C₄H₂O)CO₂CH₃)Pd(PCy₃)₂](OTf)
• CAS: 1392235-36-7
• 化学式: CF₃O₃S*C₄₃H₇₃O₃P₂Pd
• 分子量: 955.489
• InChiKey: QRFPJRSENISKJF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5-(氯甲基)-2-糠酸甲酯 、 双(三环己基膦)钯 、 silver trifluoromethanesulfonate 以 甲苯 为溶剂， 反应 1.0h， 生成 [(η³-CH₂(C₄H₂O)CO₂CH₃)Pd(PCy₃)₂](triflate) 、 [(η³-CH₂(C₄H₂O)CO₂CH₃)Pd(PCy₃)(triflato)]
  参考文献：
  名称：

  η³-Furfuryl and η³-Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

  摘要：

  A number of cationic and neutral eta(3)-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous eta(3)-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.

  DOI：

  10.1021/om300568z