[Mn(η1-NH=CPh2)(CO)3(PPh(OEt)2)2][BPh4] | 1021395-64-1

• 英文名称: [Mn(η1-NH=CPh2)(CO)3(PPh(OEt)2)2][BPh4]
• CAS: 1021395-64-1
• 化学式: C₂₄H₂₀B*C₃₆H₄₁MnNO₇P₂
• 分子量: 1035.84
• InChiKey: QHSCCGMFPJHBAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯甲酮亚胺 、 tricarbonylhydridomanganese(I)(PPh(OEt)2)2 、 四苯硼钠 、 三氟甲烷磺酸甲酯 在 triflic acid 作用下， 以 甲苯 为溶剂， 以61%的产率得到[Mn(η1-NH=CPh2)(CO)3(PPh(OEt)2)2][BPh4]
  参考文献：
  名称：

  Preparation of benzophenone imine complexes of transition metals

  摘要：

  Benzophenone imine [M(eta(1)-NH=CPh2)(CO)(n)P5-n] BPh4 [M = Mn, Re; n = 2, 3; P = P(OEt)(3), PPh(OEt)(2), PPh2OEt, PPh3] complexes were prepared by allowing triflate M(K-1-OTf)(CO)(n)P5-n compounds to react with an excess of the imine. Hydride-imine [MH(eta(1)-NH=CPh2)P-4]BPh4 (M = Ru, Os), triflate-imine [Os(k(1)-OTf)(eta(1)-NH=CPh2)P-4]BPh4 and bis(imine) [Ru(eta(1)-NH= CPh2)(2) P-4](BPh4)(2) [P = P(OEt)(3)] derivatives were also prepared. The complexes were characterized spectroscopically (IR, H-1, P-31, C-13 NMR) and a geometry in solution was also established. Hydride-benzophenone imine [IrHCl(eta(1)-NH=CPh2)LdPPh(3))(2)]BPh4 and [IrHCl(eta(NH)-N-1= CPh2)LdAsPh(3))(2)] BPh4 [L = P(OEt)(3) and PPh(OEt)(2)] complexes were prepared by reacting hydride IrHCl2L(PPh3)(2) and IrHCl2L(AsPh3)(2) precursors with an excess of imine. Dihydride IrH2(eta(1)-NH=CPh2)(PPh3)(3) complex was also obtained and a geometry in solution was proposed. (C) 2006 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.12.001