1-ethenyl-(4-(4'-isobutyl-3',4'-dihydrooxazol-2'-yl)phenyl)-1'-ethenyl-(4-(4'-ethyl-3',4'-dihydrooxazol-2'-yl)-phenyl)ferrocene | 685087-96-1

• 英文名称: 1-ethenyl-(4-(4'-isobutyl-3',4'-dihydrooxazol-2'-yl)phenyl)-1'-ethenyl-(4-(4'-ethyl-3',4'-dihydrooxazol-2'-yl)-phenyl)ferrocene
• CAS: 685087-96-1
• 化学式: C₃₈H₄₀FeN₂O₂
• 分子量: 612.595
• InChiKey: GTYZTQJEVVOPFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  DL-亮氨醇 、 1-ethenyl-(4-(4'-ethyl-3',4'-dihydrooxazol-2'-yl)phenyl)-1'-ethenyl-(4-cyanophenyl)ferrocene 在 zinc(II) chloride 作用下， 以 甲苯 为溶剂， 以11%的产率得到1-ethenyl-(4-(4'-isobutyl-3',4'-dihydrooxazol-2'-yl)phenyl)-1'-ethenyl-(4-(4'-ethyl-3',4'-dihydrooxazol-2'-yl)-phenyl)ferrocene
  参考文献：
  名称：

  Novel ferrocenyl-oxazoline ligands: first preparation of non-symmetrical bis(oxazoline)

  摘要：

  New ferrocenyl-arenylethenyl-oxazoline derivatives have been prepared (5-10) from the mono- and (1,1')-disubstituted (nitrile-ethenylaryl)ferrocene compounds (1 and 2) and the appropriated beta-aminoalcohol (3 and 4) in one step synthesis. The X-ray crystal structure of one of the ferrocenyl-ethenylaryl-oxazoline (5) is described, revealing the unusual quasi-planarity of the oxazoline ring with the phenyl and cyclopentadienyl cycles. Two compounds end-capped (9 and 10) with both, nitrile and oxazoline groups, are the key intermediates to obtain the non-symmetrical bis(oxazoline) 11, containing two different substituted heterocycles. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.10.013