[Ni2(N-(2-pyridylmethyl)N',N'-diethylethylenediamine)2(μ1,1-N3)2(N3)2] | 875634-00-7

• 英文名称: [Ni2(N-(2-pyridylmethyl)N',N'-diethylethylenediamine)2(μ1,1-N3)2(N3)2]
• CAS: 875634-00-7
• 化学式: C₂₄H₄₂N₁₈Ni₂
• 分子量: 700.098
• InChiKey: VVKHQNDBCDRWPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 N,N-diethyl-N'-(pyrid-2-ylmethyl)ethylenediamine 、 sodium azide 以 甲醇 、 水 为溶剂， 以68%的产率得到[Ni2(N-(2-pyridylmethyl)N',N'-diethylethylenediamine)2(μ1,1-N3)2(N3)2]
  参考文献：
  名称：

  Synthesis, structure and magnetic properties of two end-on double azido bridged nickel(II) dinuclear entities incorporating N,N,N-coordinating tridentate reduced Schiff base ligands

  摘要：

  Complexes of the general formula [Ni2L2(mu(1.1)-N-3)(2)(N-3)(2)] have been synthesised in good yields by reacting Ni(NO3)(2)center dot 6H(2)O with L in the presence of excess of sodium azide in methanol at room temperature. Here L is N,N-bis(2-pyridylmethyl)amine (L-1) and N-(2-pyridylmethyl)-N',N'-diethylethylenediamine (L-2). The X-ray structures of both compounds reveal that the N,N,N coordinating reduced Schiff bases are ligated facially. The Ni-N-azido-Ni angle is similar to 100 degrees and the Ni center dot center dot center dot Ni separation is similar to 3.2 angstrom. The variable temperature magnetic susceptibility measurements of the two complexes show ferromagnetic behavior. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.06.059