[RuCl(CO)(PPh3)(H-pybox)][BF4] | 1309436-72-3

• 英文名称: [RuCl(CO)(PPh3)(H-pybox)][BF4]
• 英文别名: [RuCl(CO)(PPh3)(2,6-bis[oxazolin-2-yl]pyridine)]
• CAS: 1309436-72-3
• 化学式: BF₄*C₃₀H₂₆ClN₃O₃PRu
• 分子量: 730.856
• InChiKey: MNTMEHPRPWMZMC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  一氧化碳 、 trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)] 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以95%的产率得到[RuCl(CO)(PPh3)(H-pybox)][BF4]
  参考文献：
  名称：

  Mononuclear ruthenium(II) complexes bearing the (S,S)-iPr-pybox ligand

  摘要：

  The complexes trans-[RuCl2(L){(S,S)-Pr-i-pybox}] ((S,S)-Pr-i-pybox 2,6-bis[4'-(S)-isopropyloxazolin-2'-yl] pyridine, L - PMe3 (1), P(OMe)(3) (2), PPh2(CH2CH=CH2) (3), CNBn (5), CNCy (6) and MeCN (7)) have been synthesized by substitution of ethylene on the precursor trans-[RuCl2(eta(2)-C2H4){(S,S)-Pr-i-pybox}]. This complex also reacts with cyclooctadiene (cod) or norbornadiene (nbd) and NaPF6, in refluxing methanol, giving the coordination compounds [RuCl(eta(4)-cod){(S,S)-Pr-i-pybox}][PF6] (8) and [RuCl(eta(4)-nbd){(S,S)-Pr-i-pybox}][ PF6] (9). The structures of complexes [RuCl(CO)(PPh3)(H-pybox)][BF4] (H-pybox = 2,6-bis(dihydrooxazolin-2'-yl)pyridine) (4), 6 and 8, have been resolved by X-ray diffraction methods. The catalytic activity of the new complexes in transfer hydrogenation of acetophenone has also been examined. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.02.025