mer,cis-[ruthenium(II)Cl(η3-NN'N-2,6-bis[(dimethylamino)methyl]pyridine)(NCCH3)]Cl | 286453-89-2

• 英文名称: mer,cis-[ruthenium(II)Cl(η3-NN'N-2,6-bis[(dimethylamino)methyl]pyridine)(NCCH3)]Cl
• CAS: 286453-89-2
• 化学式: C₁₅H₂₅ClN₅Ru*Cl
• 分子量: 447.373
• InChiKey: SQNHMUVHLWQREC-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [Ru2Cl4(η(3)-2,6-(Me2NCH2)2C5H3N)(μ-N2)] 、 乙腈 以 乙腈 为溶剂， 以89%的产率得到mer,cis-[ruthenium(II)Cl(η3-NN'N-2,6-bis[(dimethylamino)methyl]pyridine)(NCCH3)]Cl
  参考文献：
  名称：

  Reactivity of the binuclear ruthenium ‘Pincer’ complex [{RuCl2(η3-NN′N)}2(μ-N2)] towards N-donor ligands. The X-ray crystal structure of [RuCl2(η3-NN′N)(NCPh)] (NN′N=2,6-bis[(dimethylamino)methyl]pyridine)

  摘要：

  Treatment of the binuclear, dinitrogen-bridged complex [{RuCl2(eta(3)-NN'N)}(2)(mu-N-2)] (3, NN'N = 2,6-bis[(dimethylamino)methyl]pyridine) with two equivalents of acetonitrile gives the mononuclear derivative mer, trans-[RuCl2(eta(3)-NN'N)(NCMe)] (4), while the use of an excess of this ligand leads to the formation of the monocationic isomers mer,trans-[RuCl(eta(3)-NN'N)(NCMe)(2)]Cl (5) and mer,cis-[RuCl(eta(3)-NN'N)(NCMe)(2)]Cl (6). In contrast, when 3 is treated with an excess of benzonitrile or pyridine, the only products formed are mer, trans-[RuCl2(eta(3)-NN'N)(NCPh)] (7) and mer, trans-[RuCl2(eta(3)-NN'N(py)] (8; py = pyridine), respectively. The X-ray structures of 7 and related reactions with other N-donor ligands are reported. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00610-6