| 327029-88-9

• CAS: 327029-88-9
• 化学式: C₁₁H₁₅IrO₂
• 分子量: 371.459
• InChiKey: QALHWEAZPJONOP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 一氧化碳 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Comparison of the Reactivity of M(allyl)₃ (M = Rh, Ir) with Donor Ligands

  摘要：

  Reactions of M(allyl)(3) [M = Rh, Ir] with a variety of donor ligands have been investigated. While both complexes are unreactive toward "hard" N- and O-donor ligands, "soft" ligands such as tolylisothiocyanate, tertiary phosphines, CO, and aryl isocyanides are readily added. Whereas ligand additions to Rh(allyl)(3) are often accompanied by reduction of the Rh(III) center, analogous reactions with Ir(allyl)(3) afford stable trivalent products containing sigma -allyl ligands. The molecular structures of several derivatives are presented, including Ir(sigma -allyl)(pi -allyl)(2)(PPh3), Ir(sigma -allyl)(2)(pi -allyl)(PMe3)(2), and Ir(sigma -allyl)(3)(C dropN-2,6-Me2C6H3)(3).

  DOI：

  10.1021/om000734k
• 作为产物：
  描述：

  、 一氧化碳 以 氘代甲苯 为溶剂， 生成 、
  参考文献：
  名称：

  Comparison of the Reactivity of M(allyl)₃ (M = Rh, Ir) with Donor Ligands

  摘要：

  Reactions of M(allyl)(3) [M = Rh, Ir] with a variety of donor ligands have been investigated. While both complexes are unreactive toward "hard" N- and O-donor ligands, "soft" ligands such as tolylisothiocyanate, tertiary phosphines, CO, and aryl isocyanides are readily added. Whereas ligand additions to Rh(allyl)(3) are often accompanied by reduction of the Rh(III) center, analogous reactions with Ir(allyl)(3) afford stable trivalent products containing sigma -allyl ligands. The molecular structures of several derivatives are presented, including Ir(sigma -allyl)(pi -allyl)(2)(PPh3), Ir(sigma -allyl)(2)(pi -allyl)(PMe3)(2), and Ir(sigma -allyl)(3)(C dropN-2,6-Me2C6H3)(3).

  DOI：

  10.1021/om000734k