[Rh(cyclooctadiene)(1,2-diaminobenzene)]ClO4 | 149361-19-3

• 英文名称: [Rh(cyclooctadiene)(1,2-diaminobenzene)]ClO4
• CAS: 149361-19-3
• 化学式: C₁₄H₂₀N₂Rh*ClO₄
• 分子量: 418.682
• InChiKey: HZLBSBOQCRGLIL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Rh(cyclooctadiene)(1,2-diaminobenzene)]ClO4 在 CO 作用下， 以 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Rhodium(I) complexes with aromatic diamines

  摘要：

  The reaction of [{Rh(L2)Cl}2] (L2 = cyclo-octa-1,5-diene (COD), norbornadiene (NBD)) and 3,4-diaminotoluene (dat), 1,2-diaminobenzene (daphen)or 2,3-diaminopyridine (dapy), irrespective of the stoichiometric ratios employed, gave [Rh2(COD)2Cl2(LL)] or pentacoordinate [Rh(Cl)(NBD)(LL)] when LL = dat or daphen, and tetracoordinate [Rh(Cl)(diolefin)(LL)] when LL - dapy, bonded through the pyridine nitrogen. Mixtures of [(Rh(CO)2Cl)2] and LL(1/1) gave [Rh(CO)2(LL)][Rh(CO)2Cl2] when LL = dat, daphen or dapy. In solution, [Rh2(COD)2Cl2(LL)] or [Rh(Cl)(NBD)(LL)] is in equilibrium with the corresponding [Rh(L2)(LL)]+ cations. At low temperature, the cationic species becomes predominant. Dapy is usually. monodentate through the pyridine nitrogen if a coordinating anion, such as chlorine, is present. If not, chelate coordination through both amino groups occurs.

  DOI：

  10.1016/0022-328x(93)80253-8
• 作为产物：
  描述：

  bis(cyclooctadiene)rhodium(I) perchlorate 、 邻苯二胺 以 二氯甲烷 为溶剂， 以83%的产率得到[Rh(cyclooctadiene)(1,2-diaminobenzene)]ClO4
  参考文献：
  名称：

  Rhodium(I) complexes with aromatic diamines

  摘要：

  The reaction of [{Rh(L2)Cl}2] (L2 = cyclo-octa-1,5-diene (COD), norbornadiene (NBD)) and 3,4-diaminotoluene (dat), 1,2-diaminobenzene (daphen)or 2,3-diaminopyridine (dapy), irrespective of the stoichiometric ratios employed, gave [Rh2(COD)2Cl2(LL)] or pentacoordinate [Rh(Cl)(NBD)(LL)] when LL = dat or daphen, and tetracoordinate [Rh(Cl)(diolefin)(LL)] when LL - dapy, bonded through the pyridine nitrogen. Mixtures of [(Rh(CO)2Cl)2] and LL(1/1) gave [Rh(CO)2(LL)][Rh(CO)2Cl2] when LL = dat, daphen or dapy. In solution, [Rh2(COD)2Cl2(LL)] or [Rh(Cl)(NBD)(LL)] is in equilibrium with the corresponding [Rh(L2)(LL)]+ cations. At low temperature, the cationic species becomes predominant. Dapy is usually. monodentate through the pyridine nitrogen if a coordinating anion, such as chlorine, is present. If not, chelate coordination through both amino groups occurs.

  DOI：

  10.1016/0022-328x(93)80253-8