[Cu(N,N'-bis(2-aminopropyl)oxamide)(2-(4-carboxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide(1-))2] | 866722-74-9

• 英文名称: [Cu(N,N'-bis(2-aminopropyl)oxamide)(2-(4-carboxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide(1-))2]
• CAS: 866722-74-9
• 化学式: C₃₆H₄₈Cu₂N₈O₁₀
• 分子量: 879.917
• InChiKey: FXXOJUUMIJSDNR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 Cu(N,N'-bis[3-(methylamino)propyl]oxamide) 、 2-(4-羧基苯基)-4,4,5,5-四甲基咪唑啉-1-氧基-3-氧化物 以 甲醇 、 水 为溶剂， 以34%的产率得到[Cu(N,N'-bis(2-aminopropyl)oxamide)(2-(4-carboxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide(1-))2]
  参考文献：
  名称：

  A new heterospin complex from oxamide-bridged Cu(II) binuclear units and carboxy-phenyl-substituted nitronyl nitroxide

  摘要：

  A new heterospin complex 1, [Cu-2(oxpn)(NITPBA)(2)], derived from trans-oxamido-bridged copper(II) binuclear units [Cu-2(oxpn), oxpn = N,N'-bis(2-aminopropyl)oxamide] and carboxyl-substituted nitronyl nitroxide, (NITPBAH = 2-(4-carboxyphenyl)-4,4,5,5-tetramethyl-4,1-dihydro- 1H-imidazol-1-oxyl-3-oxide), has been synthesized and characterized structurally and magnetically. The complex 1 is a four-spin system. The magnetic susceptibility of 1 was measured over the range 2-300 K, which shows that there are unusually moderate antiferromagnetic-interactions between two copper(II) ions bridged by the oxamato bridge. (C) 2005 Published by Elsevier B.V.

  DOI：

  10.1016/j.inoche.2005.02.015