[Ru4(μ4-η2-PhC2Ph)2(CO)11](2-) | 849699-78-1

• 英文名称: [Ru4(μ4-η2-PhC2Ph)2(CO)11](2-)
• CAS: 849699-78-1
• 化学式: C₃₉H₂₀O₁₁Ru₄
• 分子量: 1068.86
• InChiKey: SSIDRLXZBXNVCS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Ru4(CO)11(μ4-C2Ph2)2 在 Bu₄NPF₆ 作用下， 以 1,2-二氯乙烷 为溶剂， 生成 [Ru4(μ4-η2-PhC2Ph)2(CO)11](2-)
  参考文献：
  名称：

  A Combined Spectroelectrochemical and Computational Study of the Chemically Reversible 2-Electron Reduction of [Ru₄(μ-RC₂R)₂(CO)₁₁] Clusters

  摘要：

  The 62-CVE clusters Ru-4(mu-RC2R)(2)(CO)(11), which feature a dodecahedral cluster core, are readily reduced to a 64-CVE dianion in a process that is essentially chemically reversible. A combination of electrochemical, spectroelectrochemical, and computational analyses of the system indicates that the first formed dianion, which features a square planar arrangement of the metal centers with the alkyne ligands located on opposite faces of the M-4 square and oriented in a manner such that the C-C bonds are perpendicular to each other, undergoes a thermal rearrangement giving a product in which the alkyne vectors lie parallel to each other across the metal framework.

  DOI：

  10.1021/om049457y