[FcC(O)]2CH(η4-C7H9)Fe(CO)3 | 277317-04-1

• 英文名称: [FcC(O)]2CH(η4-C7H9)Fe(CO)3
• CAS: 277317-04-1
• 化学式: C₃₃H₂₈Fe₃O₅
• 分子量: 672.123
• InChiKey: QUYVHOPZHWJLNI-MVFYVKPLSA-N

反应信息

• 作为产物：
  描述：

  tricarbonyl(cycloheptadienyl)iron(II) tetrafluoroborate 、 1,3-diferrocenylpropane-1,3-dione 在 KH 作用下， 以 四氢呋喃 为溶剂， 以56%的产率得到[FcC(O)]2CH(η4-C7H9)Fe(CO)3
  参考文献：
  名称：

  Kohlenwasserstoffverbrückte Metallkomplexe, XLVIII. Addition von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketonaten an koordinierte, ungesättigte Kohlenwasserstoffe von kationischen Komplexen

  摘要：

  The enolates of bis(ferrocenyl)-1.3-diketones are added to coordinated ethylene, cyclohexa- and cycloheptadienyl and heptatrienyl ligands of cationic complexes to give C-C coupling and formation of polynuclear compounds 1-10 and 13-15. Also palladium complexes of bis(ferrocenyl)-1,3-diketonates can function for these reactions. The structure of Fc-C(O)-CH[CH(2)CH(2)Fc(CO)(2)Cp]-C(O)-Fc was determined by X-ray diffraction. Threefold addition of [(eta(5)-C-6H7)Fe(CO)(3)](+) to the ligands of Co(acac)(3) was observed. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00005-x