| 105102-04-3

• CAS: 105102-04-3
• 化学式: C₁₉H₅MnO₁₅Os₃
• 分子量: 1098.78
• InChiKey: RXQBJJGLLGWCMM-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  以 苯 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine

  摘要：

  Photolysis of the heterometallic complex (mu-H)Os-3{mu-O2CC5H4Mn(CO)(3)}(CO)(10) together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os-3 metallocycle to afford the complexes (mu-H)Os-3{mu-O2CC5H4Mn(CO)(2)PPh3}(CO)(10), (mu-H)Os-3{mu-O2CC5H4Mn(CO)(3)}(CO)(9)PPh3, and (mu-H)Os-3{mu-O2CC5H4Mn(CO)(2)PPh3}(CO)(9)PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)(3) group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (mu-H)Os-3(mu-O2CC5H4R)(CO)(10) (R = H, Et).

  DOI：

  10.1007/bf02495496
• 作为产物：
  描述：

  decacarbonyl-1κ(4)C,2κ(3)C,3κ(3)C-μ-hydrido-2:3κ(2)H-μ-hydroxy-2:3κ(2)O-trisosmium-(3 Os-Os) 、 cymantrenecarboxylic acid 以 四氢呋喃 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Maksakov, V. A.; Podberezskaya, N. V.; Zavodnik, V. E., Koordinatsionnaya Khimiya, 1986, vol. 12, p. 655 - 662

  摘要：

  DOI：

文献信息

• Introduction of n-donor ligands into trinuclear osmium hydridocarbonyl clusters
  作者：V. A. Maksakov、V. A. Ershova、I. V. Bragina

  DOI：10.1007/bf00953053

  日期：1985.12