[n-Bu4N][MeGa(t-BuPO2(OH))3] | 349487-16-7

• 英文名称: [n-Bu4N][MeGa(t-BuPO2(OH))3]
• CAS: 349487-16-7
• 化学式: C₁₃H₃₃GaO₉P₃*C₁₆H₃₆N
• 分子量: 738.512
• InChiKey: PTTSFKRCOJJVIW-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrabutylazanium,fluoride,hydrofluoride 、 [t-BuPO3GaMe]4 以 四氢呋喃 、 二氯甲烷 为溶剂， 以68%的产率得到[n-Bu4N][MeGa(t-BuPO2(OH))3]
  参考文献：
  名称：

  Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion

  摘要：

  Reaction of t-BuP(O)(OSiMe3)(OH) with Me3Al leads to the formation of [Me2Al(mu -O)(2)P(OSiMe3)(t-Bu)](2) (1) whereas Me2AlCl reacts with Ph2P(O)(OH) to yield [(Cl)(Me)Al(mu -O)(2)PPh2](2) (2). These compounds represent the first examples of functionalized dimeric four-ring type aluminophosphonate systems. The double four-ring type gallophosphonate, namely, [t-BuPO3GaMe](4), reacts with n-Bu4NHF2 under ambient conditions, resulting in the formation of a monomeric gallophosphonate [n-Bu4N][MeGa(t-BuPO2(OH))(3)] (3) These derivatives have been adequately characterized using various spectroscopic techniques and X-ray diffraction studies.

  DOI：

  10.1021/ic000797v