C2H5OC(O)CH(CH3)CH2SnCl3*2hexamethylphosphoramide | 261960-93-4

• 英文名称: C2H5OC(O)CH(CH3)CH2SnCl3*2hexamethylphosphoramide
• CAS: 261960-93-4
• 化学式: C₁₈H₄₇Cl₃N₆O₄P₂Sn
• 分子量: 698.626
• InChiKey: PDSAYIMARNJSDG-KOTSIBKOSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六甲基磷酰三胺 、 C2H5OC(O)CH(CH3)CH2SnCl3*hexamethylphosphoramide 以 二氯甲烷 为溶剂， 以67%的产率得到C2H5OC(O)CH(CH3)CH2SnCl3*2hexamethylphosphoramide
  参考文献：
  名称：

  Synthesis and Structural Characterization of the Complexes of 2-alkoxycarbonylpropyltin Trichlorides with Iiexamethylphosphoramide and N-(2-hydroxyphenyl)-2-hydroxy-L-naphthylaldimine

  摘要：

  The complexes of 2-alkoxycarbonylpropyltin trichlorides with hexamethylphosphoramide (HMPA) and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine (H2L) have been synthesized and characterized by means of elemental analyses, IR and H-1 NMR spectra and an X-ray single crystal diffraction study. The spectral data indicate that these complexes are all six-coordinate tin compounds. The crystal structure of MeOCO-CH(CH3)CH2SnCl3. HMPA shows that the tin atom adopts a distorted octahedral geometry via the oxygen atoms of HMPA and intramolecular carbonyl group.

  DOI：

  10.1080/00945710009351764