| 1449328-76-0

• CAS: 1449328-76-0
• 化学式: C₅₄H₇₂Cl₃LiN₄O₃Zn₂
• 分子量: 1069.27
• InChiKey: ZHTJCEAEDJPRRU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二苯甲酮腙 在 sodium sulfate 、 potassium hydroxide 、 mercury(II) oxide 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 18.0h， 生成
  参考文献：
  名称：

  Diazo Compounds as Electrophiles To React with 1,4-Dilithio-1,3-dienes: Efficient Synthesis of 1-Imino-pyrrole Derivatives

  摘要：

  1-Imino-pyrrole and indole derivatives were synthesized in high yields from the reaction of diaryl diazomethanes with 1,4-dilithio-1,3-dienes. Diaryl diazomethanes reacted as electrophiles in this reaction. An unprecedented Zn-complex was formed via transmetalation of the above reaction intermediate with ZnCl2 and was structurally characterized. The trans-mu(2)-eta(1):eta(1) coordination mode in the solid state for this azaallylzinc compound was observed.

  DOI：

  10.1021/ol401878q