| 238760-27-5

• CAS: 238760-27-5
• 化学式: C₃₂H₂₃AuF₅Fe₂P
• 分子量: 842.161
• InChiKey: XMNPWSBEZSVGIQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  bis(ferrocenyl)phenylphosphine 、 pentafluorophenyl(tetrahydrothiophene)gold(I) 以 二氯甲烷 为溶剂， 以66%的产率得到
  参考文献：
  名称：

  Synthesis of gold-(I) and -(III) complexes with diferrocenylphenylphosphine (PFc2Ph). Crystal structure of [Au(PFc2Ph)2]ClO4

  摘要：

  Diferrocenylphenylphosphine (PFc(2)Ph) reacts with gold(I) derivatives to afford neutral, [AuR(PFc(2)Ph)] (R = Cl, C6F5) or cationic complexes, [Au(PFc(2)Ph)(PR3)]ClO4 (PR3 = PFc(2)Ph, PPh3). Reaction with [Au(C6F5)(3)(OEt2)] or [Au(C6F5)(2)Cl](2) gives the gold(III) complexes [Au(C6F5)(3)(PFc(2)Ph)] or [Au(C6F5)(2)Cl(PFc(2)Ph)], respectively. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01224-8