2-dichloro-(2-diphenylphosphinomethyl-1-diphenylphosphine-8-trimethoxysilyl octane)palladium(II) | 208837-90-5

• 英文名称: 2-dichloro-(2-diphenylphosphinomethyl-1-diphenylphosphine-8-trimethoxysilyl octane)palladium(II)
• CAS: 208837-90-5
• 化学式: C₃₆H₄₆Cl₂O₃P₂PdSi
• 分子量: 794.118
• InChiKey: SJNMDZSDTRYVCO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 1-diphenylphosphanyl-2-diphenylphosphanylmethyl-8-(trimethoxysilyl)octane 以 四氢呋喃 为溶剂， 生成 2-dichloro-(2-diphenylphosphinomethyl-1-diphenylphosphine-8-trimethoxysilyl octane)palladium(II)
  参考文献：
  名称：

  Supported organometallic complexes XVI

  摘要：

  The dppp ligand 4(T-0) being provided with a T-silylfunctionalized (CH2)(6) spacer in the symmetric position of the C3 bridge is obtained by a simple three step reaction starting with 2-hydroxymethyl-1-hydroxy-7-octene (1) (Scheme 1). 1 is chlorinated to the dichloride 2 which can be hydrosilylated with HSi(OMe)(3) to give 3(T-0). Finally both chlorine atoms in 3(T-0) are exchanged by PPh2. Treatment of (COD)PdCl2 with 4(T-0) results in the formation of the T-silylfunctionalized palladium complex 5(T-0). (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00374-x